The biggest confusion that some students face in thermodynamics is different sign conventions of "work" in chemistry and physics... i have gone through the same situation...
let me clear this confusion..
In chemistry and physics sign conventions of work are opposite because of which it seems that equation of first law of thermodynamics is different for chemistry and physics.
The equation is..
PHYSICS - dQ=dE+W
CHEMISTRY - dE=dQ+W
where "Q"is heat,"E" is internal energy and "W" is work done.
WORK
EXPANSION- work done by the system
COMPRESSION- work done on the system
SIGN CONVENTION
PHYSICS
let me clear this confusion..
In chemistry and physics sign conventions of work are opposite because of which it seems that equation of first law of thermodynamics is different for chemistry and physics.
The equation is..
PHYSICS - dQ=dE+W
CHEMISTRY - dE=dQ+W
where "Q"is heat,"E" is internal energy and "W" is work done.
WORK
EXPANSION- work done by the system
COMPRESSION- work done on the system
SIGN CONVENTION
PHYSICS
- Expansion - positive
- Compression - negative
- Expansion - negative
- Compression - positive
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